well, vultures have a 120cm range rather than 30cm and while an 8BP barrage is nice and all, it lacks the concentrated tank-killing power of the vultures, vultures also have a 45cm shooting attack after they fire their one-shot missiles, rather than 30cm of valks
I've used vultures quite a bit and a double followed by shoot can hit almost anything on the table pretty hard, they are very good for shooting up engines of vaul, gunforts, warhounds, and most 5+ save APC type vehicles (rhinos, razorbacks, preds, falcons, battlewagons, speeders, vypers etc etc) they can also pop up and hit the other side of the table without needing to get into harm's way
that being said, they're probably not as good a choice as they are pretty fragile, a stormtrooper formation needs 3 times as many blast markers to break and is far less vulnerable to being engaged, but they fulfil very very different roles
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