Ok: I seem to have a reasonable method set up now for open top moulds. It's slightly different from pouring silicone so I'll detail it here:
1. Build lego box (if lego isn't a household good, it should be)
2. line box with clingfilm. I normally only bother with the bottom, but doing the sides too would save me a lot of grief.
3. Squirt large amount of silcone caulk into box. It's best to leave the nozzle off the gun to get a nice thick dollop.
4. place clingfilm over box and squash silicone flat with your fingers. Doing it from the center out will eliminate most airbubbles, and all of the ones in the top 5mm that we care about.
5. wipe origional with suitable mold release. KY jelly works fine. Peel back cling film and gently press the piece in. The silicone is thick enough to hold it up without support. (NB this means a non-horizontal mold line is near impossible to do)
6. Leave it in a very well ventilated area (preferably outside) to cure. The gas given off is basically evaporated vinegar. It's not dangerous unless you have a wife or girlfriend or a valuable marble statue nearby. Typically after a few hours I take the base off the mold to double the curing area.
I'm working in a hot and humid tropical country, so curing might take longer for you. The silicone shrinks very slightly as it cures, so if you leave it to set for a good while you'll get sharper edges then if you remove the original early.
7. Optional 2 part mold development.
- after step 5, wipe top and surface of silicone with ky jelly (best to be generous here), build a second layer of box with lego and squeeze in more slicone, cover in clingfilm and press down, remove clingfilm to aid curing. This experiment is still running, I think i may have separated the halves and removed the original too soon (curing time logically s a function of mold thickness) but we'll see.

1-part 'robo claw' mold. looking at the left 2 parts of the pink cast, I removed the originals from the mold 18hrs earlier: you can see how they're more rounded then the right hand parts.
Pink is the one part petro resin glue. As said previously, it's a bit soft and hard to get a decent edge in, but is easy and cheap for one part molds.
white is pure superglue. IF you want to try casting anything in superglue, don't.
1) you will glue the mold to the table, your fngers to the table, some sprue to your fingers, the bottle to the table ect.
2) It shrinks a lot. maybe 50% volume lost.
3) It's really difficult to get out of molds, even silicone ones. You will damage the mold each time
4) it's brittle. of three claws cast, only one came out whole.
I think i once experimented with superglue and tissue to try and make it more stable and less brittle, resin glue is easier.
I was worried it'd be too soft to support the weight of the demon engine, but as you can see, no problem.
next i think i'll try some real resin. Maybe make a batch and then pour every mould i still have to see results.